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Feature 2 Murata's New Businesses - A Step Taken for the Future

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CO2-Capturing Ceramics

Development of Ceramics that Absorb Carbon Dioxide

New Materials with a Potential Role in Global Warming Prevention

Conventional CO2 reduction strategies have focused on emissions control through energy reduction. However, in recent years CO2 absorbent materials that recover gases after emission have also attracted attention. Murata is also currently involved in the development of such promising CO2 reduction technologies, focusing on highly functional materials that can absorb approximately 100 times their own volume of carbon dioxide.

Murata has been researching effective uses for the ceramic waste materials generated by its existing capacitor production processes. In 2005, we invented efficient CO2 absorption and desorption functions at high temperatures in barium orthotitanate (Ba2TiO4) synthesized using barium titanate, which is a raw material for one of the Company's major products, ceramic capacitors. Since 2006, we have been developing experimental prototypes in collaboration with a CO2 recovery equipment manufacturer and are currently conducting evaluation tests.

Barium orthotitanate is characterized by stable performance at high temperatures and durability against sustained usage. It can be used at temperatures exceeding 900°C, well outside the ranges allowed by conventional absorbent materials (100-200°C), which eliminates the need for cooling CO2 prior to recovery. Accordingly, this substance has potential applications with such high-volume, high-temperature CO2 producers as power generation plants and iron and steel works.

If applied to removing high-temperature CO2 generated in the hydrogen gas fuel production process for fuel cells, it will facilitate generation of 98% concentration hydrogen.

Furthermore, as the CO2 is recovered at a high temperature, it can easily be used as a material to synthesize other useful substances.

Barium orthotitanate, as a CO2-capturing ceramic, assists the recycling of waste materials from the capacitor production process, helping to prevent global warming. In addition, it can supply other production processes with CO2, rendering it a multipurpose, highly functional material.

Yoshinori Sato

Yoshinori Sato
Materials Development Management
Division, R&D Center

Potential Applications in Hydrogen Filling Stations

Fuel cells that can act as power sources without generating CO2 are anticipated for next-generation automotive applications, although CO2 is emitted as a byproduct when generating the hydrogen these cells uses as fuel.

Accordingly, applying barium orthotitanate to CO2 absorption equipment at hydrogen filling stations could resolve this issue. This in turn could be a step toward the construction of the hydrogen society that is envisioned for the future.

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